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January 1, 1992Journal of the Chemical Society Chemical Communications

A novel B–H⇀Ru agostic bond. Crystal structure of [RuCl{7,8-µ-S(CH 2 CH 2 )S-C 2 B 9 H 10 }(PPh 3 ) 2 ]·Me 2 CO

Francesç Teixidor José A. Ayllón Clara Viñas Raikko Kivekäs Reijo Sillanpää Jaume Casabó

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Abstract

The complex [RuCl{7,8-µ-S(CH2CH2)S-C2B9H10}(PPh3)2]·Me2CO 1 contains octahedral ruthenium(II), the sixth coordination site being occupied by an agostic B–H⇀Ru in the first example of B(3)–H⇀Ru coordination in the solid state; solution NMR studies show the presence of B(3)–Ru–H bonding.

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Teixidor et al. (1992) studied this question.

synapsesocial.com/papers/6a912a2931838a9342d2c276 https://doi.org/10.1039/c39920001281

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