The three‐dimensional, homogeneous, and heterogeneous polymerizations in systems monoglycol or diglycol monomethacrylate–dimethacrylates of glycols in various solvents were studied dilatometrically. The network density and the content of pendant vinyl groups were determined at various conversions. The influence of physical crosslinks formed by hydrophobic crosslinking agents was estimated by the comparison with copolymers of diglycol monomethacrylate–methyl methacrylate. By correlation of kinetics of polymerization with the three‐dimensional network formation, it was possible to characterize the polymerizing systems within the whole range of conversion.
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Kopec̆ek et al. (1967) studied this question.
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