Tuning the topology of a 2D metal–organic framework from 2D to 3D using modulator assisted synthesis

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Two new metal-organic frameworks based on 2,2'-bipyridine-4,4'-dicarboxylate and La(III) ions were prepared under solvothermal conditions. [La(bpda)3/2(dmf)2]·dmf·H2O, MSU-10, was isolated as a 2D network structure but by introducing a modulator, 1,10-phenanthroline,...