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Get cross! A cruciform 6,6′-dipentacenyl, Dip-TIPS, was prepared as a unique semiconductor with two-dimensional isotropic face-to-face π-stacking in the crystal structure. High FET mobilities were obtained from the vapor-deposited thin films. The use of cruciform molecules in the design of organic semiconductors is a new concept that is expected to diminish the effect of molecular orientation on device performance.
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Zhang et al. (2009) studied this question.
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