A dinuclear manganese(II) complex [Mn2(L)(PhCO2)2(NCS)][L = 2,6-bis{N-[2-(dimethylamino)ethyl]iminomethyl}-4-methylphenolate(1–)] decomposes H2O2 catalytically indimethylformamidesolution; two oxomanganese(IV) species {MnIV(O)}2 and MnIIMnIV(O) are detected for the first time as intermediates in the H2O2 disproportionation reaction based on mass spectrometric and visible spectral studies.
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Sakiyama et al. (1993) studied this question.
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