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Non- C 2 -symmetric ( N -alkyl, N -aryl)-hybrid chiral NHC/Cu(I) complex catalyzed asymmetric hydroboration of N -benzoyl aldimines has been developed. The reaction proceeded smoothly at room temperature, giving α-amido boronic esters in excellent yields (up to 94%) and good enantioselectivities (up to 86% ee).
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Tian et al. (2013) studied this question.
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