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January 1, 1995Recueil des Travaux Chimiques des Pays-Bas

Synthesis of enantiomerically pure tricarbonylchromium(0) complexes of ortho substituted styrenes from (S)‐α‐Methylbenzylamine

Paul W. N. Christian Susan E. Gibson Richard Gil P. Caroline V. Jones Carlos F. Marcos Frank Prechtl Adam T. Wierzchleyski

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Abstract

Tricarbonylchromium(0) complexes of sulfur, phosphorus, silicon, iodine, tin and carbon substituted (S)‐(α‐methylbenzyl)dimethylamines are oxidized by dimethyldioxirane to enantiomerically pure tricarbonylchromium(0) complexes of substituted styrenes; the reactions proceed via a chemoselective oxidation of the tertiary amines to their N‐oxides, one of which was isolated, and a subsequent Cope reaction.

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Cite This Study

Christian et al. (1995) studied this question.

synapsesocial.com/papers/6a9379c56b15b2b1a50aa9df https://doi.org/10.1002/recl.19951140411

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