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Self‐assembly reactions of sulfonates with AgNO3 in the presence of secondary N‐ or P‐containing ligands result in the formation of four new silver‐sulfonate polymers, [Ag(PIP)]n·[Ag(pesp)]n·2nH2O (1), [Ag2(pesp)(dabco)]n·5nH2O (2), [{Ag(pesp)1/2(hmt)1/4}·0.5H2O]n (3) and [Ag(PPh3)(pesp)1/2]n·nMeOH (4), whose structures change from one‐dimensional chains to three‐dimensional open frameworks based on the secondary ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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Sun et al. (2004) studied this question.
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