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Nearly D3h symmetry, a planar Sn3N framework, almost symmetrical SnClSn bridges and extremely short SnN bonds-these are the features of the skeleton of (ClMe2Sn)3N 1. This unusual structure has been characterized by NMR spectroscopy, quantum chemical calculations, and X-ray structural analysis. No indications of SnN (dp)π bond participation were found.
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Kober et al. (1993) studied this question.
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