Determining Eight Biogenic Amines in Surface Water Using High-Performance Liquid Chromatography–Tandem Mass Spectrometry

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A method for determining eight biogenic amines in surface water was established using high-performance liquid chromatography-triple quadrupole mass spectrometry to improve on the detection sensitivity of current methods. The limits of detection and quantification were 0.05 and 0.2 g L -1 , respectively, for histamine, cadaverine, spermine, and spermidine, 1.0 and 3.0 g L -1 , respectively, for putrescine, 1.5 and 5.0 g L -1 , respectively, for tyramine and tryptamine, and 2.0 and 5.0 g L -1 , respectively, for 2-phenylethylamine. The recovery of biogenic amines from spiked water samples was between 97.3 and 108.6% at levels between 0.05 and 15 g L -1 (R > 0.999). The relative standard deviations were in the range of 0.10-0.29%. This method can achieve rapid and accurate determination of biogenic amines in surface water, and it meets the minimum residue measurement requirements.