The high mobility of the C22− ligand in trinuclear complexes of the type [M]3C2 (shown schematically) and alkynyl-bridged [M]2C2R complexes provides information for attaining a better understanding of the topomerization processes of alkyne complexes and alkynes via vinylidene complexes [M]CCR2 and vinylidenes :CCR2, respectively, in which the carbon atoms exchange their positions.
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Uwe Rosenthal (2003) studied this question.
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