A review of our studies of the inverse electron demand Diels‐Alder reactions of heteroaromatic and acyclic azadienes is presented and the application of a N‐sulfonyl‐1‐aza‐1,3‐butadiene [4+2] cycloaddition reaction in the total synthesis of natural and ent‐fredericamycin A is described in detail.
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Dale L. Boger (1996) studied this question.
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