Transition Metal‐Catalyzed Directing‐Group‐Assisted C−H Activation of Phenols

Strategies that exploit directing groups to control the site selectivity in the C-H activation of arenes have received much attention during the past two decades. In light of the importance of phenol derivatives in the areas of pharmaceuticals, agrochemicals, and materials science, transition-metal-catalyzed C-H activation of phenols has proven to be an extremely useful tool in organic synthesis. This Minireview summarizes the current state-of-the-art direct C-H activation of phenol derivatives under transition-metal catalysis.