A series of new complexes is reported with phosphorus oxychloride as a ligand: viz., complexes of Mg(II), Ca(II), Sr(II), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II). Reflection spectra in the visible and near infrared region indicate an octahedral configuration of the metal ion and the POCl3 molecules.
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Driessen et al. (1968) studied this question.
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