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Abstract o-Fluorophenyl glycine and alanine, 2-thienyl glycine and alanine form with dinuclear, chloro bridged metal complexes the chiral N, O-chelates (arene)M (Cl)(NH2CHRCO2) (M = Ru, Rh, Ir; arene = cymene, Cp*) and (R3P)(Cl)M(NH2CHRCO2) (M = Pd, Pt) as mixtures of diastereoisomers or cis/trans-isomers, respectively.
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Koch et al. (2001) studied this question.
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