Raman microscopy of lateral epitaxial overgrowth of GaN on sapphire

We have used confocal Raman microscopy to investigate lateral epitaxially overgrown (LEO) GaN on sapphire substrates. The one-phonon Raman spectra are consistent with pyramidal growth of the GaN before coalescence has occurred. The position and asymmetric line shape of the A1 longitudinal optical (LO) phonon demonstrate that the LEO GaN is doped. The dopant is most likely Si from the SiN mask used to produce the LEO GaN. The carrier concentration is estimated to be 1×1017 cm−3. We have also used Raman microscopy to spatially resolve the yellow emission from different regions of the LEO GaN.