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In hypergolic propellants, hypergolicity is an extremely important parameter in evaluating fuels. In this study, a new family of hypergolic metal (Cu2+, Ni2+, Zn2+) complexes with B12H122– were synthesized and fully characterized. Two of these six complexes exhibited ultrashort ignition delay times (ca. 1 ms), with white fuming nitric acid as the oxidizer, besides good physicochemical properties (decomposition temperatures: 221.8–286.3 °C; densities: 1.215–1.264 g cm–3). The results demonstrate their promising applications in bipropellant formulations.
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Zhang et al. (2018) studied this question.
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