Zwitterionic fused pyrazolo-triazole based high performing energetic materials

A series of nitrogen-rich fused energetic materials were synthesized from commercially available inexpensive starting materials and fully characterized using 1H and 13C NMR, IR spectroscopy, elemental analysis, and DSC. The structure of zwitterionic compound 2 was supported by SCXRD data. Among all, 3 and 4 possess excellent detonation velocity (8956 and 9163 m s-1) and are insensitive towards friction (>360 N) and impact (10 J), having moderate to excellent thermal stability (171-262 °C). It is worth mentioning that the zwitterionic fused pyrazolo-triazole compound 2 and its energetic salts offer remarkable performance as new-generation thermally stable energetic materials.