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January 1, 1991Journal of the Chemical Society Chemical Communications

Hydrogen loss from pentamethylcyclopentadienyl–ruthenium complexes; the synthesis and X-ray structure of [Ru(C 5 Me 4 CH 2 Cl)Cl 3 (Me 2 S)]

Chunhong Wei Franklin I. Aigbirhio Harry Adams Neil A. Bailey Paul D. Hempstead Peter M. Maitlis

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Abstract

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Reaction of [{C5Me5RuCl2}2] with Me2SO (in air in CHCl3) gives [(C5Me4CH2)RuCl2(Me2SO)], 2a; this reacts with HCl to give [(C5Me4CH2Cl)RuCl3(Me2S)](also in high yield), characterised by an X-ray structure determination.

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Cite This Study

Wei et al. (1991) studied this question.

synapsesocial.com/papers/6a9633c7b9656a0f92bad499 https://doi.org/10.1039/c39910000883

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