Michael additions, Knoevenagel condensations, and epoxidation of enones with H2O2 can be catalyzed under mild conditions with a new mesoporous base. Equation (a) shows the principle for a Michael addition (X = CN, Y = CO2Et); the catalyst is obtained by immobilization of a guanidine base in MCM-41.
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Rao et al. (1997) studied this question.
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