A Slater-Koster tight binding fitting scheme is presented for the band structure of the group V 2H layer compounds. This is used to fit to the 'd' and 'p' bands of NbSe 2 and NbS 2 as calculated by the layer method. Details are given of the symmetrisation throughout the hexagonal Brillouin zone. From the fit the densities of states are calculated and the results discussed.
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Doran et al. (1978) studied this question.
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