A supramolecular recognition interface is formed through the self-assembly of cyclic D,L-peptides. Phenyl–phenyl interactions direct the solid-state organization of dimeric peptide cyclo[(-L-Phe-D-MeN-Ala-L-hPhe-D-MeN-Ala)2] (1) by forming clusters of edge-to-face contacts between dimers (shown left), which suggests that these peptide scaffolds may be useful subunits for crystal engineering.
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Bong et al. (2001) studied this question.
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