The taming of the shrew! For the first time, a broadly applicable efficient room-temperature Arbuzov rearrangement is described. This reaction is accomplished through an atom-economical Lewis acid catalyzed process (see scheme, TMSOTf=trimethylsilyl trifluoromethanesulfonate). The method has been generalized to primary and activated secondary phosphites, phosphinites, and phosphonites.
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Renard et al. (2003) studied this question.
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