The use of GPC coupled with a multiangle laser light scattering photometer for the characterization of polymers. On the determination of molecular weight, size and branching

The use of gel permeation chromatorgraphy (GPC) coupled with the multiangle laser light scattering (MALLS) detector for the determination of molecular weight and size distribution and for the identification of polymer branching is demonstrated on several examples of both organic and water souluble polymers. The influence of the second virial coefficient and the way of the light scattering data evaluation on the results obtained is shown. Measurements of the root mean square radius are presented for two series of polystyrene and polymethylmethacrylate standard, and the results are compared with the radii calculated from the Flory‐Fox equation.