A window of opportunity: The ligand-centred redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb-doped SnO2 film attached to a transparent conducting substrate and cycling the applied potential through the catecholate/semiquinone redox couple.
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Garcı́a-Cañadas et al. (2003) studied this question.
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