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Four ternary liquid−liquid(−liquid) equilibria in the systems aniline + cyclohexylamine (CHA) + water, aniline + CHA + octane, aniline + water + octane, and aniline + water + toluene under atmospheric pressure at (298.15 and 333.15) K are reported. The measurements were carried out by turbidity titration, gas−liquid chromatography analyses, Karl Fischer, and potentiometric titration. Predictions of the NRTL and UNIQUAC Gibbs energy models are shown based only on binary parameters of simultaneous fitting of available vapor−liquid equilibria and liquid−liquid equilibria data. In this context P − x data were measured for the system aniline + octane at 383.15 K.
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Grenner et al. (2006) studied this question.
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