Melting and Sintering of a Body-Centered Cubic Superlattice of PbSe Nanocrystals Followed by Small Angle X-ray Scattering

The structural evolution of a body-centered cubic (bcc) superlattice of 6.6 nm diameter organic ligand-coated PbSe nanocrystals was studied in situ by small angle X-ray scattering (SAXS) as it was heated in air from room temperature to 350°C. As it was heated above room temperature, the superlattice contracted slightly, but maintained bcc structure up to 110°C. Once the temperature rose above 110°C, the superlattice began to disorder, by first losing long-range translational order and then local positional order. At temperatures exceeding 168°C, the nanocrystals sintered and oxidized, transforming into PbSeO(3) nanorods.