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The de Haas-van Alphen effect of the stage-1 intercalated compound SbCl 5 graphite consists of a dominant oscillation of frequency 1211 T and two weaker oscillations with frequencies 1110 and 1026 T. The cyclotron mass of the carrier with the dominant oscillation is 0.271 m 0 where m 0 is the free-electron mass. The dominant oscillation is explained by the linear combination of atomic orbitals calculation of Holzwarth (1980) with electron transfer from the graphite of 0.37 electrons per SbCl 5 molecule. The amplitudes of the two smaller oscillations depend on the length of time that a sample is exposed to air. The frequencies are attributed to environment-related aging processes in the compound. Methods of preparation of pure, homogeneous and stable stage-1 samples are also described.
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Zaleski et al. (1984) studied this question.
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