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A novel μ(2)-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear , in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.
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Braunschweig et al. (2013) studied this question.
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