Picosecond transient absorption measurements and simulations of the hydrated electron geminate recombination dynamics are presented for 4 eV multiphoton ionization of liquid H 2 O and D 2 O. To within the accuracy of the data and simulation, the isotope effect can be accounted for in terms of the decrease in the diffusion coefficients for e aq -, D 3 O +, and OD • and the e aq - + D 3 O + → D reaction rate in D 2 O.
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Crowell et al. (1996) studied this question.
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