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The mechanism of nucleophilic opening of epoxide rings has been investigated by studying the kinetics of (i) . amine-epoxide reactions both in the absence and presence of hydroxyl-containing catalysts, () reactions of commercial epoxydiane oligomers of different molecular weights with aromatic diamines (m -phenylene diamine), and (ili) reactions of epoxides with phenols in the absence and presence of alkali.
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N. S. Enikolopiyan (1976) studied this question.
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