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A modification of van der Waals and Platteeuw's (1959) hydrate equilibrium model which incorporates the effect of spherical asymmetry is developed. A corresponding states correlation is used to predict the deviation of Langmuir constants from ideal values. In this model the Kihara parameters obtained from hydrate equilibrium data agree well with those obtained from virial coefficient data.
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John et al. (1985) studied this question.
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