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The line shapes of saturation spectroscopy in optically thick two-level media are calculated for atomic and molecular transitions. Line narrowing and distortion effects due to propagation are presented. For Doppler-broadened media it is shown that, due to multiphoton processes, the natural linewidth limits the ultimate narrowing that can be reached. Thus, up to α₀L=20, only when the rate-equation approximation is valid subhomogeneous linewidths are expected.
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Lorenzo-Filho et al. (1998) studied this question.
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