Formulation of a non-equilibrium model of an ionic system with a narrow acid–base boundary (representing the “electrolyte diode”) is introduced and its predictions are compared with those based on the traditional simplified model with a local electroneutrality and instantaneous local dissociation equilibria assumptions. Significant differences have been found in the spatial profiles around the acid–base boundary.
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Šnita et al. (2002) studied this question.
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