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A series of novel monobenzyl-substituted deuteriofullerenes (BnDCs) were synthesized efficiently through Co-catalyzed selective monofunctionalization of C60. Bulk heterojunction solar cells, based on poly(3-hexylthiophene) as the donor and BnDCs as the acceptors, exhibited higher photovoltaic performances as compared to the corresponding protonated BnHCs devices.
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Lu et al. (2013) studied this question.
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