A convenient microemulsion-mediated hydrothermal process was employed for the first synthesis of BaF2 whiskers with lengths up to 50 mum and aspects ratios as high as 1000, each of which is a single crystal with a growth direction of (111). A directed aggregation growth process mediated by the microemulsion droplet building blocks is proposed for the formation of BaF2 whiskers.
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Cao et al. (2003) studied this question.
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