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A modified Dubinin–Radushkevich (D–R) equation is proposed for the excess adsorption isotherm. It is shown that the equation describes the experimental excess adsorption isotherm excellently over a very wide range of gas equilibrium pressures. An algorithm is presented for the convertion of measurable values of excess adsorption to absolute values.
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Serpinski et al. (1993) studied this question.
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