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Simple and versatile: A new zinc complex catalyzes the intramolecular hydroamination of nonactivated alkynes and alkenes (see example in scheme; {(iPr)2ATI}=N-isopropyl-2-(isopropylamino)troponiminato). The catalyst is relatively robust, exhibits excellent activities, and tolerates various functional groups such as ethers, thioethers, and amides.
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Zulys et al. (2005) studied this question.
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