January 1, 2014Chemical ScienceOpen Access

Selective radical amination of aldehydic C(sp 2 )–H bonds with fluoroaryl azides via Co( ii )-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditions

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Abstract

-fluoroaryl amides in good to excellent yields. A series of mechanistic studies support a stepwise radical mechanism for the Co(II)-catalyzed intermolecular C-H amination.

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Jin et al. (2014) studied this question.

synapsesocial.com/papers/6a9bd16e6aa4d2b65295487c https://doi.org/10.1039/c4sc00697f

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Abstract

-fluoroaryl amides in good to excellent yields. A series of mechanistic studies support a stepwise radical mechanism for the Co(II)-catalyzed intermolecular C-H amination.

Selective radical amination of aldehydic C(sp 2 )–H bonds with fluoroaryl azides via Co( ii )-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditions

Abstract

Discussion

Cite This Study

Selective radical amination of aldehydic C(sp 2 )–H bonds with fluoroaryl azides via Co( ii )-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditions

Abstract

Discussion

Cite This Study

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