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September 5, 2026EnergiesOpen Access

Photo-Electrocatalytic Hydrogen Production Emphasising Process Scalability

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Authors

NANikolaos ArgirusisPGPantelitsa GeorgiouIKIrene A. Kanellopoulou

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Overview

Review demonstrates hurdles in scaling photoelectrochemical water splitting, highlighting reactor design and material needs against photovoltaic electrolysis.

Key Points

  • To review the progress, technical bottlenecks, and scalability pathways of photoelectrochemical water splitting systems for large-scale solar hydrogen production.
  • Conducted a comprehensive literature analysis evaluating semiconductor materials, reactor architectures, and scalable artificial leaf systems.
  • Synthesized technical benchmarks comparing photoelectrochemical technologies to competitive photovoltaic-driven electrolysis.
  • Evaluated scaling requirements through the lens of pilot-scale implementation, field deployment, life-cycle analysis, and techno-economic feasibility.
  • Laboratory-scale efficiencies in photoelectrochemical water splitting struggle to compete commercially with rapidly maturing photovoltaic-electrolysis systems.
  • Identified biomimetic Z-scheme and S-scheme catalyst architectures as promising pathways to improve charge separation and overall solar-to-hydrogen conversion efficiency.
  • Established that bridging the laboratory-to-industry gap requires targeted advances in semiconductor durability, scalable photoreactor design, and rigorous field testing.

Cite This Study

Argirusis et al. (2026) studied this question.

synapsesocial.com/papers/6a9bd48c6b95aff0620ec398https://doi.org/10.3390/en19174177
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