Experimental study demonstrates palladium-catalyzed coupling of secondary allylic boronic esters with iodoarenes, indicating regioselectivity governed by olefin substitution.
Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.
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Glasspoole et al. (2011) studied this question.
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