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The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].
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Ingleson et al. (2004) studied this question.
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