An unconventional hydrate promoter, tBuNH2 , forms a double hydrate upon reacting with CH4 (see picture). This double hydrate shows different storage capacities for CH4 depending on the concentration of tBuNH2. Based on this phenomenon, a tuning concept for determining the optimum initial concentration of tBuNH2 is proposed.
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Kim et al. (2005) studied this question.
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