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Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity.
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Xu et al. (2007) studied this question.
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