Solidification of the liquid medium in ceramic suspensions containing less than a critical volume fraction powder leads to the formation of particle‐free dendrites of the frozen medium. These particle‐free dendrites create, after sublimation of the frozen vehicle, large dendrite pores. We define the conditions under which particle‐free dendrites form, and relate the size and volume fraction of the dendrites to the volume fraction powder and the solidification rate.
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Shanti et al. (2006) studied this question.
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