An investigation was carried out on branching of polymers obtained by lauroyl‐peroxide or by radiation‐initiated polymerization of vinylchloride. As a result, branching shows no dependence on conversion and could be ascribed, at least partially, to the presence of CH2Cl‐side groups. A reaction mechanism for this type of branching was proposed.
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Rigo et al. (1972) studied this question.
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