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We have established practical protocols to the stereoselective synthesis of syn- and anti-β-amino alcohols via the electrophile-promoted intramolecular amination of trichloroacetimidates derived from allylic and homoallylic alcohols. Stereoselective total synthesis of natural products containing β-amino alcohol functionality has been achieved by means of these methods.
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Lee et al. (2004) studied this question.
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