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The di-μ-oxo-tetrakis(2,2′-bipyridine)dimanganese complex was used as a heterogeneous phase catalyst for water oxidation by adsorbing into Kaolin clay. The oxygen evolved was analyzed by gas chromatography and mass spectrometry. The water oxidation reaction involving the four-electron process in a heterogeneous phase was discussed.
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Ramaraj et al. (1987) studied this question.
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