The methane and isobutane chemical ionization mass spectra of ten 2,4,6‐trinitroaromatic compounds have been recorded. The mass spectra contain intense [M + 1]+ ions and usually little fragmentation. However, in some cases major fragmentation processes have been observed. Some unusual adduct ions have been found with isobutane as the reagent and their temperature dependence has been studied.
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Zitrin et al. (1976) studied this question.
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