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A new diphosphonate-functionalized polyoxomolybdate L,D-(NH4)6{MoV2O4[(MoVI2O6)NH3CH2CH2CH2C(O)(PO3)2]2}·10H2O (1) has been synthesized by the reaction of alendronic acid with {Mo2O4(H2O)6}2+ fragments. In the structure, a restriction of “folding” alkyl induced chiral polyoxometalate has been observed.
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Tan et al. (2010) studied this question.
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